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Direct Palladium-Catalyzed Intermolecular Allylation of Highly Electron-Deficient Polyfluoroarenes

Authors

  • Shilu Fan,

    1. Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Science, 345 Lingling Lu, Shanghai 200032 (China), Fax: (+86) 21-6416-6128
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  • Fei Chen,

    1. Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Science, 345 Lingling Lu, Shanghai 200032 (China), Fax: (+86) 21-6416-6128
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  • Prof. Dr. Xingang Zhang

    Corresponding author
    1. Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Science, 345 Lingling Lu, Shanghai 200032 (China), Fax: (+86) 21-6416-6128
    • Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Science, 345 Lingling Lu, Shanghai 200032 (China), Fax: (+86) 21-6416-6128
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  • This work was financially supported by the NSFC (20902100, 20832008), the Shanghai Rising-Star Program (09QA1406900), and the SIOC. We thank Prof. Wei-Liang Duan and Prof. Shu-Li You for helpful discussions.

Abstract

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Ganz einfach: Der Einsatz von einfach erhältlichem PPh3, hohe Reaktionseffizienz und gute Stereo- und Regioselektivität ergeben einen einfachen Zugang zu polyfluorarylierten Allylderivaten (siehe Schema; phen=1,10-Phenanthrolin). Der Mechanismus der Titelreaktion wurde untersucht.

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