Berichtigung: C[BOND]H Bond Functionalization in Water Catalyzed by Carboxylato Ruthenium(II) Systems

Authors

  • Percia B. Arockiam,

  • Dr. Cédric Fischmeister,

  • Dr. Christian Bruneau,

  • Prof. Pierre H. Dixneuf

Errata

This article corrects:

  1. C[BOND]H Bond Functionalization in Water Catalyzed by Carboxylato Ruthenium(II) Systems Volume 122, Issue 37, 6779–6782, Article first published online: 27 July 2010

In dieser Zuschrift (DOI: ) ist die vierte Spalte von Tabelle 3 (Reaktionszeiten t) falsch beschriftet, und bei den Einträgen 6–8 finden sich falsche Werte. Die korrekte Tabelle ist hier gezeigt.

Table 3. Functionalization of heteroarylbenzene derivatives.[a]inline image
EntryT [°C]Solventt [h]Conv [%]Productm/d(yield)[b]
  1. [a] Heteroarylbenzene (0.5 mmol), A (5 mol %) KOPiv (20 mol %), K2CO3 (3 equiv). Het-X (1.25 mmol; see text for the identity of Het-X in each entry), 2 mL of water. [b] Yield of isolated product in parenthesis.

1100H2O NMP10 10100 99
original image
1/99 (89) 2/98
2100H2O NMP10 10100 99
original image
1/99 (92) 3/97
3100H2O NMP20 20100 70
original image
0/100 (41) 38/62
4100 40H2O H2O2 62100 100
original image
0/100 (94) 3/97 (90)
5100H2O10100
original image
4/96 (90)
6100H2O NMP14 14100 95
original image
3/97 (95) 64/36
7100H2O NMP30 30100 95
original image
3/97 (48) 17/83
8100H2O16100
original image
– (83)

Ancillary