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Covalently Linked Porphyrin–La@C82 Hybrids: Structural Elucidation and Investigation of Intramolecular Interactions

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  • This work was supported in part by a Grant-in-Aid for Scientific research on Innovative Areas (No. 20108001, “pi-Space”), a Grant-in-Aid for Scientific Research (A) (No. 20245006), The Next Generation Super Computing Project (Nanoscience Project), Nanotechnology Support Project, and Grants-in-Aid for Scientific research on Priority Area (Nos. 20036008, 20038007), and Specially Promoted Research from the Ministry of Education, Culture, Sports, Science, and Technology of Japan. Technology of Japan and The Strategic Japanese–Spanish Cooperative Program is funded by JST and MICINN.

Abstract

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π-π-Unterhaltung: Drei isomere Porphyrin-La@C82-Hybride wurden erstmals synthetisiert und strukturell charakterisiert (siehe Bild: La blaue Kugel, N dunkelblau, O rot). Die beiden Chromophore, die große π-Oberflächen aufweisen, zeigen offensichtliche elektronische Wechselwirkungen im Grundzustand und kommunizieren miteinander im photoangeregten Zustand.

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