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Tunable Carbonyl Ylide Reactions: Selective Synthesis of Dihydrofurans and Dihydrobenzoxepines

Authors

  • Dr. Jiao-Long Zhou,

    1. The State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai, 200032 (China), Fax: (+86) 21-5492-5078
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  • Dr. Yong Liang,

    1. Beijing National Laboratory of Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing, 100871 (China)
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  • Chao Deng,

    1. The State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai, 200032 (China), Fax: (+86) 21-5492-5078
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  • Haolai Zhou,

    1. Beijing National Laboratory of Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing, 100871 (China)
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  • Zheng Wang,

    1. The State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai, 200032 (China), Fax: (+86) 21-5492-5078
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  • Dr. Xiu-Li Sun,

    1. The State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai, 200032 (China), Fax: (+86) 21-5492-5078
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  • Dr. Jun-Cheng Zheng,

    1. The State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai, 200032 (China), Fax: (+86) 21-5492-5078
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  • Prof. Dr. Zhi-Xiang Yu,

    Corresponding author
    1. Beijing National Laboratory of Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing, 100871 (China)
    • Beijing National Laboratory of Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing, 100871 (China)
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  • Prof. Dr. Yong Tang

    Corresponding author
    1. The State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai, 200032 (China), Fax: (+86) 21-5492-5078
    • The State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai, 200032 (China), Fax: (+86) 21-5492-5078
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  • We are grateful for the financial support from the National Natural Sciences Foundation of China (No. 20821002, 20932008, and 20825205), the Major State Basic Research Development Program (Grant No. 2009CB825300), and the Chinese Academy of Sciences. We thank Dr. Guang-Yu Li (SIOC) for NMR analysis.

Abstract

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Auswahlverfahren: Aus identischen Ausgangsverbindungen können mithilfe des jeweils geeigneten Liganden Dihydrofurane oder Dihydrobenzoxepine chemoselektiv und in mäßiger bis guter Diastereoselektivität erhalten werden (siehe Schema).

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