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Authors

  • Prof. Dr. Takahiko Kojima,

    Corresponding author
    1. Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennoudai, Tsukuba, Ibaraki 305-8571 (Japan), Fax: (+81) 29-853-4323
    • Takahiko Kojima, Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennoudai, Tsukuba, Ibaraki 305-8571 (Japan), Fax: (+81) 29-853-4323===

      Shunichi Fukuzumi, Department of Material and Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamada-oka, Suita, Osaka 565-0871 (Japan), Fax: +81-6-6879-7370===

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  • Prof. Dr. Shunichi Fukuzumi

    Corresponding author
    1. Department of Material and Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamada-oka, Suita, Osaka 565-0871 (Japan), Fax: +81-6-6879-7370
    2. Department of Bioinspired Science, Ewha Womans University, Seoul 120-750 (Korea)
    • Takahiko Kojima, Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennoudai, Tsukuba, Ibaraki 305-8571 (Japan), Fax: (+81) 29-853-4323===

      Shunichi Fukuzumi, Department of Material and Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamada-oka, Suita, Osaka 565-0871 (Japan), Fax: +81-6-6879-7370===

    Search for more papers by this author

Abstract

Vertraue Experimenten: DFT-Rechnungen besagen, dass Wasserstoffbrücken von Wassermolekülen in einem siebenfach koordinierten Ruthenium-Oxo-Komplex den Singulettgrundzustand stabilisieren. Übereinstimmend belegen Experimente für einen neuartigen siebenfach koordinierten, pentaganol-bipyramidalen Ruthenium-Oxo-Komplex einen Singulettgrundzustand. Trotzdem zeigt er die gleiche Reaktivität wie ein analoger Triplettkomplex.

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