Mesoporous Zeolite-Supported Ruthenium Nanoparticles as Highly Selective Fischer–Tropsch Catalysts for the Production of C5–C11 Isoparaffins

Authors

  • Dr. Jincan Kang,

    1. State Key Laboratory of Physical Chemistry of Solid Surfaces and National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China), Fax: (+86) 592-2183047
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  • Kang Cheng,

    1. State Key Laboratory of Physical Chemistry of Solid Surfaces and National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China), Fax: (+86) 592-2183047
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  • Lei Zhang,

    1. State Key Laboratory of Physical Chemistry of Solid Surfaces and National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China), Fax: (+86) 592-2183047
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  • Prof. Dr. Qinghong Zhang,

    Corresponding author
    1. State Key Laboratory of Physical Chemistry of Solid Surfaces and National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China), Fax: (+86) 592-2183047
    • State Key Laboratory of Physical Chemistry of Solid Surfaces and National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China), Fax: (+86) 592-2183047
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  • Jiansheng Ding,

    1. Yantai Wanhua Polyurethanes Co, LTD. Yantai 264002 (China)
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  • Dr. Weiqi Hua,

    1. Yantai Wanhua Polyurethanes Co, LTD. Yantai 264002 (China)
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  • Dr. Yinchuan Lou,

    1. Yantai Wanhua Polyurethanes Co, LTD. Yantai 264002 (China)
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  • Qingge Zhai,

    1. State Key Laboratory of Physical Chemistry of Solid Surfaces and National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China), Fax: (+86) 592-2183047
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  • Prof. Dr. Ye Wang

    Corresponding author
    1. State Key Laboratory of Physical Chemistry of Solid Surfaces and National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China), Fax: (+86) 592-2183047
    • State Key Laboratory of Physical Chemistry of Solid Surfaces and National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China), Fax: (+86) 592-2183047
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  • This work was supported by the NSF of China (20625310, 20923004, and 21033006), the National Basic Program of China (2010CB732303), the Key Scientific Project of Fujian Province (2009HZ0002-1), and the Doctoral Program of Higher Education (20090121110007).

Abstract

original image

Ein hoch selektiver Katalysator für die Produktion von C5- bis C11-Isoparaffinen aus Synthesegas beruht auf einem mesoporösen Zeolith. Die Selektivität von Ru/meso-ZSM-5 für diese Kohlenwasserstoffe reicht an 80 % heran, wobei das Verhältnis von Isoparaffinen zu n-Paraffinen 2.7:1 beträgt. Die mesoporöse Struktur und die Acidität von meso-ZSM-5 sind entscheidend für die Produktselektivität in sekundären Hydrocrack-Reaktionen.

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