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A Uniform Bimetallic Rhodium/Iron Nanoparticle Catalyst for the Hydrogenation of Olefins and Nitroarenes

Authors

  • Ikuse Nakamula,

    1. Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-0033 (Japan), Fax: (+81) 3-5841-8063
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  • Dr. Yoshinori Yamanoi,

    1. Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-0033 (Japan), Fax: (+81) 3-5841-8063
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  • Dr. Takane Imaoka,

    1. Chemical Resources Laboratory, Tokyo Institute of Technology (Japan), Fax: (+81) 45-924-5260
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  • Prof. Kimihisa Yamamoto,

    Corresponding author
    1. Chemical Resources Laboratory, Tokyo Institute of Technology (Japan), Fax: (+81) 45-924-5260
    • Chemical Resources Laboratory, Tokyo Institute of Technology (Japan), Fax: (+81) 45-924-5260
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  • Prof. Hiroshi Nishihara

    Corresponding author
    1. Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-0033 (Japan), Fax: (+81) 3-5841-8063
    • Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-0033 (Japan), Fax: (+81) 3-5841-8063
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  • This work was supported by Grant-in-Aids for Scientific Research on Innovative Areas “Coordination Programming” (area 2107, No. 21108002) and the Global COE Program for “Chemistry Innovation through the Cooperation of Science and Engineering”, from the Ministry of Education, Culture, Sports, Science, and Technology (Japan).

Abstract

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Die bessere Wahl: Rh/Fe-Dimetallnanopartikel in Dendrimeren sind bessere Katalysatoren für die Hydrierung von Olefinen als reine Rh-Nanopartikel in einem Dendrimerkäfig, und anders als der Wilkinson-Katalysator katalysieren sie auch die Nitroarenhydrierung (siehe Schema, G4=Dendrimer der 4. Generation).

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