Get access

Synthesis and Characterization of a Rhenabenzyne Complex

Authors

  • Dr. Jiangxi Chen,

    1. Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon (Hong Kong)
    Search for more papers by this author
  • Dr. Herman H. Y. Sung,

    1. Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon (Hong Kong)
    Search for more papers by this author
  • Prof. Dr. Ian D. Williams,

    1. Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon (Hong Kong)
    Search for more papers by this author
  • Prof. Dr. Zhenyang Lin,

    Corresponding author
    1. Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon (Hong Kong)
    • Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon (Hong Kong)
    Search for more papers by this author
  • Prof. Dr. Guochen Jia

    Corresponding author
    1. Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon (Hong Kong)
    • Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon (Hong Kong)
    Search for more papers by this author

  • This work was supported by the Hong Kong Research Grant Council (HKUST601007, 602611 and HKU1/CRF/08). We thank Chuan Shi for his help in the NBO analysis of complex 6.

Abstract

original image

Komplexe Umlagerungen: Rhenahydrobenzole sind mit Metallabenzolen verwandte Metallaarene (siehe Schema) und werden durch Umlagerung aus einem thermisch instabilen Rhenium-Carbin-Komplex erzeugt. Die Rhenahydrobenzol-Komplexe wurden durch Elementaranalyse, 1H-NMR-Spektroskopie und Röntgenstrukturanalyse charakterisiert. Die Ergebnisse zeigen, dass es möglich ist, Metallahydrobenzole mit verschiedenen Übergangsmetallzentren aufzubauen.

Ancillary