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DNA-Programmed Glaser–Eglinton Reactions for the Synthesis of Conjugated Molecular Wires

Authors

  • Jens B. Ravnsbæk,

    1. Danish National Research Foundation: Center for DNA Nanotechnology, Department of Chemistry and iNANO, Aarhus University, Langelandsgade 140, 8000 Aarhus C (Denmark)
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  • Mikkel F. Jacobsen,

    1. Danish National Research Foundation: Center for DNA Nanotechnology, Department of Chemistry and iNANO, Aarhus University, Langelandsgade 140, 8000 Aarhus C (Denmark)
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  • Christian B. Rosen,

    1. Danish National Research Foundation: Center for DNA Nanotechnology, Department of Chemistry and iNANO, Aarhus University, Langelandsgade 140, 8000 Aarhus C (Denmark)
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  • Niels V. Voigt,

    1. Danish National Research Foundation: Center for DNA Nanotechnology, Department of Chemistry and iNANO, Aarhus University, Langelandsgade 140, 8000 Aarhus C (Denmark)
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  • Prof. Kurt V. Gothelf

    Corresponding author
    1. Danish National Research Foundation: Center for DNA Nanotechnology, Department of Chemistry and iNANO, Aarhus University, Langelandsgade 140, 8000 Aarhus C (Denmark)
    • Danish National Research Foundation: Center for DNA Nanotechnology, Department of Chemistry and iNANO, Aarhus University, Langelandsgade 140, 8000 Aarhus C (Denmark)
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  • The work was supported by the Danish National Research Foundation.

Abstract

original image

Drahtige Selbstorganisation: Kurze Oligo(phenylenethinylen)-Einheiten (schwarze Strukturen, siehe Bild) werden durch angebundene DNA-Stränge organisiert, die auch 1,3-Verknüpfungen zwischen den Bausteinen durch eine Cu-vermittelte Glaser-Eglinton-Kupplung für die selektive Bildung von konjugierten Dimer-, Trimer- und Tetramer-Drähten von bis zu 8 nm Länge steuern.

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