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Directing Protons to the Dioxygen Ligand of a Ruthenium(II) Complex with Pendent Amines in the Second Coordination Sphere†

  1. Tristan A. Tronic1,
  2. Dr. Mary Rakowski DuBois2,
  3. Dr. Werner Kaminsky1,
  4. Michael K. Coggins1,
  5. Dr. Tianbiao Liu2,
  6. Prof. James M. Mayer1,*

Article first published online: 26 SEP 2011

DOI: 10.1002/ange.201105266

Issue

Angewandte Chemie

Angewandte Chemie

Volume 123, Issue 46, pages 11128–11131, November 11, 2011

Additional Information

How to Cite

Tronic, T. A., Rakowski DuBois, M., Kaminsky, W., Coggins, M. K., Liu, T. and Mayer, J. M. (2011), Directing Protons to the Dioxygen Ligand of a Ruthenium(II) Complex with Pendent Amines in the Second Coordination Sphere. Angew. Chem., 123: 11128–11131. doi: 10.1002/ange.201105266

Author Information

  1. 1

    Department of Chemistry, University of Washington, Box 351700, Seattle, WA 98195 (USA)

  2. 2

    Chemical and Materials Sciences Division, Pacific Northwest National Lab, Richland, WA 99352 (USA)

*Department of Chemistry, University of Washington, Box 351700, Seattle, WA 98195 (USA)

  1. †

    This work is supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under FWP 56073. We thank Dr. Rajan Paranji for NMR assistance and Dr. Jenny Yang for 15N-labeled P2N2 ligand. M.R.D. and T.L. were supported by the Division of Chemical Sciences, Biosciences and Geosciences, Office of Basic Energy Sciences, Office of Science of the U.S. Department of Energy. Pacific Northwest National Lab is operated by Battelle for the U.S. Department of Energy.

Publication History

  1. Issue published online: 8 NOV 2011
  2. Article first published online: 26 SEP 2011
  3. Manuscript Revised: 30 AUG 2011
  4. Manuscript Received: 27 JUL 2011

Funded by

  • U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. Grant Number: FWP 56073

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    Akihiro Yoshinari, Akira Tazawa, Shigeki Kuwata, Takao Ikariya, Synthesis, Structures, and Reactivities of Pincer-Type Ruthenium Complexes Bearing Two Proton-Responsive Pyrazole Arms, Chemistry – An Asian Journal, 2012, 7, 6
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