Zuschrift

Photoswitchable Dynamic Magnetic Relaxation in a Well-Isolated {Fe2Co} Double-Zigzag Chain†

  1. Dr. Da-Peng Dong1,
  2. Prof. Tao Liu1,*,
  3. Dr. Shinji Kanegawa2,
  4. Dr. Soonchul Kang2,
  5. Prof. Osamu Sato2,*,
  6. Prof. Cheng He1,
  7. Prof. Chun-Ying Duan1,*

Article first published online: 12 APR 2012

DOI: 10.1002/ange.201105987

Issue

Angewandte Chemie

Angewandte Chemie

Volume 124, Issue 21, pages 5209–5213, May 21, 2012

Additional Information

How to Cite

Dong, D.-P., Liu, T., Kanegawa, S., Kang, S., Sato, O., He, C. and Duan, C.-Y. (2012), Photoswitchable Dynamic Magnetic Relaxation in a Well-Isolated {Fe2Co} Double-Zigzag Chain. Angew. Chem., 124: 5209–5213. doi: 10.1002/ange.201105987

Author Information

  1. 1

    State Key Laboratory of Fine Chemicals, Dalian University of Technology, 2 Linggong Rd., 116024 Dalian (China)

  2. 2

    Institute for Materials Chemistry and Engineering, Kyushu University, 6-1 Kasuga, Fukuoka, 816-8580 (Japan)

*State Key Laboratory of Fine Chemicals, Dalian University of Technology, 2 Linggong Rd., 116024 Dalian (China)

  1. †

    This work was partly supported by the NSFC (Grant 21101021, 91122031, 21025102), the Fundamental Research Funds for the Central Universities, China, the Mitsubishi Foundation and Coordination Programming.

Publication History

  1. Issue published online: 15 MAY 2012
  2. Article first published online: 12 APR 2012
  3. Manuscript Revised: 9 MAR 2012
  4. Manuscript Received: 24 AUG 2011

Funded by

  • NSFC. Grant Numbers: 21101021, 91122031, 21025102
  • Mitsubishi Foundation

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Keywords:

  • Cobalt;
  • Eisen;
  • Kettenstrukturen;
  • Ladungstransfer;
  • Magnetische Eigenschaften
Thumbnail image of graphical abstract

Ein ladungstransferinduzierter Spinübergang tritt in den isolierten FeIII2CoII-Ketten von {[Fe(pzTp)(CN)3]2Co(4-Styrylpyridin)2}⋅2 H2O⋅2 CH3OH (1) auf. Bei Bestrahlung mit 532-nm-Licht zeigt 1 Einzelkettenmagnetismus, ohne antiferromagnetische Ordnung nach dem Abschalten der Bestrahlung (siehe Bild; C grau, N blau, B gelb; LS=Low Spin, HS=High Spin).

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