Enantioselective Total Syntheses of Communesins A and B

Authors

  • Zhiwei Zuo,

    1. State Key Laboratory of Bioorganic & Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032 (China)
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  • Prof. Dawei Ma

    Corresponding author
    1. State Key Laboratory of Bioorganic & Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032 (China)
    • State Key Laboratory of Bioorganic & Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032 (China)
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  • We are grateful to the National Basic Research Program of China (973 Program, grant 2010CB833200), Chinese Academy of Sciences, and the National Natural Science Foundation of China (grant 21132008 & 20921091) for their financial support.

Abstract

original image

So einfach wie A, B: Die ersten Totalsynthesen der (−)-Communesine A und B (siehe Bild) wurden fertiggestellt. Die Synthese des spiro-verknüpften Indolin-Teils erfolgte über eine intramolekulare oxidative Kupplung und die des A-Rings in einer Kaskadenreaktion.

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