Metal–Organic Framework Regioisomers Based on Bifunctional Ligands

Authors

  • Dr. Min Kim,

    1. Department of Chemistry and Biochemistry, University of California, San Diego, 9500 Gilman Drive, La Jolla, CA 92093 (USA)
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  • Jake A. Boissonnault,

    1. Department of Chemistry and Biochemistry, University of California, San Diego, 9500 Gilman Drive, La Jolla, CA 92093 (USA)
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    • These authors contributed equally to this work.

  • Phuong V. Dau,

    1. Department of Chemistry and Biochemistry, University of California, San Diego, 9500 Gilman Drive, La Jolla, CA 92093 (USA)
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    • These authors contributed equally to this work.

  • Prof. Dr. Seth M. Cohen

    Corresponding author
    1. Department of Chemistry and Biochemistry, University of California, San Diego, 9500 Gilman Drive, La Jolla, CA 92093 (USA)
    • Department of Chemistry and Biochemistry, University of California, San Diego, 9500 Gilman Drive, La Jolla, CA 92093 (USA)
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  • We thank Dr. Y. Su (UCSD) for assistance with mass spectrometry experiments and D. Martin (UCSD) for assistance with crystallography. This work was supported by a grant from the National Science Foundation (CHE-0952370).

Abstract

original image

Regioisomere MOFs: Eine Serie von difunktionellen regioisomeren Metall-organischen Gerüststrukturen (MOFs) wurde ausgehend von Aminohalogenbenzoldicarboxylat-Liganden (NH2X-BDC) hergestellt. ZrIV- und ZnII-basierte MOFs wurden synthetisiert, und bei den flexiblen ZnII-basierten MOFs hingen die Gassorptionseigenschaften vom Ligandensubstitutionsmuster ab.

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