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Circularly Polarized Lanthanide Luminescence from Langmuir–Blodgett Films Formed from Optically Active and Amphiphilic EuIII-Based Self-Assembly Complexes

Authors

  • Dr. Jonathan A. Kitchen,

    Corresponding author
    1. School of Chemistry, Centre for Synthesis and Chemical Biology, Trinity College Dublin, College Green, Dublin 2 (Ireland)
    • School of Chemistry, Centre for Synthesis and Chemical Biology, Trinity College Dublin, College Green, Dublin 2 (Ireland)
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  • Dawn E. Barry,

    1. School of Chemistry, Centre for Synthesis and Chemical Biology, Trinity College Dublin, College Green, Dublin 2 (Ireland)
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  • Dr. Laszlo Mercs,

    1. School of Chemistry and Chemical Biology, University College Dublin, Belfield, Dublin 4 (Ireland)
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  • Prof. Martin Albrecht,

    1. School of Chemistry and Chemical Biology, University College Dublin, Belfield, Dublin 4 (Ireland)
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  • Prof. Robert D. Peacock,

    1. School of Chemistry, Joseph Black Building, University of Glasgow, Glasgow, G12 8QQ (UK)
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  • Prof. Thorfinnur Gunnlaugsson

    Corresponding author
    1. School of Chemistry, Centre for Synthesis and Chemical Biology, Trinity College Dublin, College Green, Dublin 2 (Ireland)
    • School of Chemistry, Centre for Synthesis and Chemical Biology, Trinity College Dublin, College Green, Dublin 2 (Ireland)
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  • We thank the Science Foundation Ireland (SFI PI Award 2010 (TG), SFI RFP Awards 2008 and 2009 (TG), the Irish Research Council for Science, Engineering & Technology (IRCSET, Postdoctoral Fellowship to J.A.K.), and the European Research Council (StG 208561, M.A.) for financial support. We would like to thank particularly Dr. Tom McCabe for assistance in collecting X-ray data.

Abstract

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„Europische“ Union: Eine Europium(III)-gelenkte Synthese führte zu chiralen amphiphilen selbstorganisierten Komplexen, die auf Quarzträgern stabile Langmuir-Blodgett(LB)-Filme bilden. Die resultierenden Monoschichten sind die ersten Beispiele für LB-Filme mit zeitverzögerter EuIII-zentrierter Emission und zirkular polarisierter Lumineszenz (CPL).

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