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Macrocyclic Restriction with Flexible Alkylene Linkers: A Simple Strategy to Control the Solid-State Properties of π-Conjugated Systems

Authors

  • Dr. Shohei Saito,

    1. Department of Chemistry, Graduate School of Science, Nagoya University, and CREST, Japan Science and Technology Agency, Furo, Chikusa, Nagoya 464-8602 (Japan)
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  • Ken Nakakura,

    1. Department of Chemistry, Graduate School of Science, Nagoya University, and CREST, Japan Science and Technology Agency, Furo, Chikusa, Nagoya 464-8602 (Japan)
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  • Prof. Dr. Shigehiro Yamaguchi

    Corresponding author
    1. Department of Chemistry, Graduate School of Science, Nagoya University, and CREST, Japan Science and Technology Agency, Furo, Chikusa, Nagoya 464-8602 (Japan)
    • Department of Chemistry, Graduate School of Science, Nagoya University, and CREST, Japan Science and Technology Agency, Furo, Chikusa, Nagoya 464-8602 (Japan)
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  • This work was supported by CREST (JST). The authors thank Prof. K. Awaga and Dr. H. Yoshikawa (Nagoya University) for the SEM and diffuse reflectance measurements and T. Hikage (High Intensity X-ray Diffraction Laboratory, Nagoya University) for powder XRD measurements.

Abstract

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Cyclisch und flexibel: Ein einfaches molekulares Design wird vorgeschlagen, mit dem sich die Molekülpackung und Festkörpereigenschaften π-konjugierter Gerüste kontrollieren lassen. Feine Unterschiede in der Länge der flexiblen Alkylenbrücke cyclischer Terthiophendimere führen zu charakteristischen Molekülpackungen mit entsprechend spezifischen Festkörpereigenschaften, wie etwa Gelbildungsvermögen und photophysikalischen Eigenschaften.

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