Zuschrift

Mechanoradicals Created in “Polymeric Sponges” Drive Reactions in Aqueous Media†

  1. Dr. H. Tarik Baytekin,
  2. Dr. Bilge Baytekin,
  3. Prof. Bartosz A. Grzybowski*

Article first published online: 1 MAR 2012

DOI: 10.1002/ange.201108110

Issue

Angewandte Chemie

Angewandte Chemie

Volume 124, Issue 15, pages 3656–3660, April 10, 2012

Additional Information

How to Cite

Baytekin, H. T., Baytekin, B. and Grzybowski, B. A. (2012), Mechanoradicals Created in “Polymeric Sponges” Drive Reactions in Aqueous Media. Angew. Chem., 124: 3656–3660. doi: 10.1002/ange.201108110

Author Information

  1. Department of Chemistry and Department of Chemical and Biological Engineering, Northwestern University, 2145 Sheridan Road, Evanston 60208 IL (USA) http://dysa.northwestern.edu

*Department of Chemistry and Department of Chemical and Biological Engineering, Northwestern University, 2145 Sheridan Road, Evanston 60208 IL (USA) http://dysa.northwestern.edu

  1. †

    This work was supported by the Non-equilibrium Energy Research Center (NERC) which is an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Award Number DE-SC0000989. We would like to thank Prof. Michael R. Wasielewski and Dr. Tomoaki Miura for their help with ESR spectroscopy, Dr. Bartlomiej Kowalczyk for SEM imaging, Pat Fuller for his help in radical diffusion simulations, and Prof. Fraser J. Stoddart and Albert C. Fahrenbach for CV measurements. XPS spectrum was taken at the KECK-II facility at NU. H.T.B and B.B. contributed equally to this work.

Publication History

  1. Issue published online: 4 APR 2012
  2. Article first published online: 1 MAR 2012
  3. Manuscript Revised: 2 FEB 2012
  4. Manuscript Received: 17 NOV 2011

Funded by

  • U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. Grant Number: DE-SC0000989

SEARCH

SEARCH BY CITATION

ARTICLE TOOLS

View Full Article with Supporting Information (HTML) Get PDF (1322K)

Keywords:

  • Mechanochemie;
  • Polymerchemie;
  • Radikale;
  • Wasserstoffperoxid
Thumbnail image of graphical abstract

H2O2auf Druck hin: Die makroskopisch reversible Verformung von Polymeren in Kontakt mit Wasser ergibt genug H2O2 für chemische Synthesen im kleinen Maßstab. Die Menge an mechanisch synthetisiertem H2O2 nimmt bei Vergrößerung der Polymer-Wasser-Grenzfläche zu; in weichen, porösen Polymer-„Schwämmen“ ist ein Wirkungsgrad von 30 % für die Umwandlung von mechanischer in chemische Energie erreichbar.

View Full Article with Supporting Information (HTML) Get PDF (1322K)