Maximizing Field-Effect Mobility and Solid-State Luminescence in Organic Semiconductors

Authors

  • Afshin Dadvand,

    1. Department of Chemistry and Centre for Self-Assembled Chemical Structures, McGill University, 801 Sherbrooke Street West, H3 A 2K6 Montreal, QC (Canada)
    2. INRS—Énergie, Matériaux et Télécommunications (Canada)
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  • Dr. Andrey G. Moiseev,

    1. Department of Chemistry and Centre for Self-Assembled Chemical Structures, McGill University, 801 Sherbrooke Street West, H3 A 2K6 Montreal, QC (Canada)
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  • Kosuke Sawabe,

    1. Department of Physics, Graduate School of Science, Tohoku University (Japan)
    2. Graduate School of Advanced Science and Engineering, Waseda University (Japan)
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  • Wei-Hsin Sun,

    1. Department of Chemistry and Centre for Self-Assembled Chemical Structures, McGill University, 801 Sherbrooke Street West, H3 A 2K6 Montreal, QC (Canada)
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  • Dr. Brandon Djukic,

    1. Department of Chemistry and Centre for Self-Assembled Chemical Structures, McGill University, 801 Sherbrooke Street West, H3 A 2K6 Montreal, QC (Canada)
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  • Insik Chung,

    1. Department of Chemistry and Centre for Self-Assembled Chemical Structures, McGill University, 801 Sherbrooke Street West, H3 A 2K6 Montreal, QC (Canada)
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  • Prof. Taishi Takenobu,

    1. Graduate School of Advanced Science and Engineering, Waseda University (Japan)
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  • Prof. Federico Rosei,

    1. INRS—Énergie, Matériaux et Télécommunications (Canada)
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  • Prof. Dmitrii F. Perepichka

    Corresponding author
    1. Department of Chemistry and Centre for Self-Assembled Chemical Structures, McGill University, 801 Sherbrooke Street West, H3 A 2K6 Montreal, QC (Canada)
    • Department of Chemistry and Centre for Self-Assembled Chemical Structures, McGill University, 801 Sherbrooke Street West, H3 A 2K6 Montreal, QC (Canada)
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  • This work was funded by the NSERC of Canada through Discovery Grants and a CRD grant supported by Plasmionique Inc. We are grateful to the CFI and NSERC for infrastructure support. F.R. acknowledges the Canada Research Chairs program for partial salary support. We acknowledge Prof. G. Hanan and F. Belanger (University of Montreal) for access to lifetime measurements and X-ray analysis, respectively.

Abstract

original image

Organische Transistoren aus dem gezeigten Styrylanthracen zeigen hohe Ladungsträgermobilitäten und Lumineszenz-Quantenausbeuten, was dem Fehlen eines strahlungslosen Zerfalls des Singulettzustands zugeschrieben wird; demnach wäre es fraglich, dass die für eine hohe Mobilität benötigten effizienten π-Wechselwirkungen stets zu einer Emissionslöschung führen. Die Transistoren zeigen eine blaue Elektrolumineszenz und bleiben bei Betrieb und Lagerung stabil.

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