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Rhodium Dinaphthocyclooctatetraene Complexes: Synthesis, Characterization and Catalytic Activity in [5+2] Cycloadditions†

  1. Prof. Paul A. Wender*,
  2. Adam B. Lesser,
  3. Lauren E. Sirois

Article first published online: 1 FEB 2012

DOI: 10.1002/ange.201108270

Issue

Angewandte Chemie

Angewandte Chemie

Volume 124, Issue 11, pages 2790–2794, March 12, 2012

Additional Information

How to Cite

Wender, P. A., Lesser, A. B. and Sirois, L. E. (2012), Rhodium Dinaphthocyclooctatetraene Complexes: Synthesis, Characterization and Catalytic Activity in [5+2] Cycloadditions. Angew. Chem., 124: 2790–2794. doi: 10.1002/ange.201108270

Author Information

  1. Department of Chemistry, Department of Chemical and Systems Biology, Stanford University, Stanford, CA 94305-5080 (USA) http://www.stanford.edu/group/pawender/

*Department of Chemistry, Department of Chemical and Systems Biology, Stanford University, Stanford, CA 94305-5080 (USA) http://www.stanford.edu/group/pawender/

  1. †

    We thank the National Science Foundation (CHE-0450638) for an NSF Graduate Research Fellowship (L.E.S.) and Amgen and Eli Lilly (A.B.L.) for financial support. We also thank Allen Oliver at the University of Notre Dame for X-ray crystal structures. Justin P. Christy is acknowledged for his supporting work on the syntheses of COTs and for helpful discussions.

Publication History

  1. Issue published online: 7 MAR 2012
  2. Article first published online: 1 FEB 2012
  3. Manuscript Revised: 27 DEC 2011
  4. Manuscript Received: 23 NOV 2011

Funded by

  • National Science Foundation. Grant Number: CHE-0450638
  • NSF
  • Amgen
  • Eli Lilly

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Keywords:

  • Cycloadditionen;
  • Cyclooctatetraen;
  • Nickel;
  • Rhodium;
  • Übergangsmetallkatalyse
Thumbnail image of graphical abstract

Hochaktiv und kompatibel: Eine Ni0-katalysierte [2+2+2+2]-Cycloaddition führt zur effizienten skalierbaren Synthese des Liganden Dinaphtho[a,e]cyclooctatetraen (dnCOT). dnCOT koordiniert mit RhI zu [Rh(dnCOT)(MeCN)2]SbF6 (siehe Schema), einem exzellenten Katalysator für [5+2]-Cycloadditionen von Vinylcyclopropanen mit π-Systemen, der außerordentlich kompatibel mit funktionellen Gruppen ist.

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