An Amine-Functionalized Titanium Metal–Organic Framework Photocatalyst with Visible-Light-Induced Activity for CO2 Reduction

Authors

  • Yanghe Fu,

    1. Research Institute of Photocatalysis, Fujian Provincial Key Laboratory of Photocatalysis, State Key Laboratory Breeding Base, Fuzhou University, Fuzhou 350002 (People's Republic of China)
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  • Dengrong Sun,

    1. Research Institute of Photocatalysis, Fujian Provincial Key Laboratory of Photocatalysis, State Key Laboratory Breeding Base, Fuzhou University, Fuzhou 350002 (People's Republic of China)
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  • Yongjuan Chen,

    1. Research Institute of Photocatalysis, Fujian Provincial Key Laboratory of Photocatalysis, State Key Laboratory Breeding Base, Fuzhou University, Fuzhou 350002 (People's Republic of China)
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  • Renkun Huang,

    1. Research Institute of Photocatalysis, Fujian Provincial Key Laboratory of Photocatalysis, State Key Laboratory Breeding Base, Fuzhou University, Fuzhou 350002 (People's Republic of China)
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  • Dr. Zhengxin Ding,

    1. Research Institute of Photocatalysis, Fujian Provincial Key Laboratory of Photocatalysis, State Key Laboratory Breeding Base, Fuzhou University, Fuzhou 350002 (People's Republic of China)
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  • Prof. Dr. Xianzhi Fu,

    1. Research Institute of Photocatalysis, Fujian Provincial Key Laboratory of Photocatalysis, State Key Laboratory Breeding Base, Fuzhou University, Fuzhou 350002 (People's Republic of China)
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  • Prof. Dr. Zhaohui Li

    Corresponding author
    1. Research Institute of Photocatalysis, Fujian Provincial Key Laboratory of Photocatalysis, State Key Laboratory Breeding Base, Fuzhou University, Fuzhou 350002 (People's Republic of China)
    • Research Institute of Photocatalysis, Fujian Provincial Key Laboratory of Photocatalysis, State Key Laboratory Breeding Base, Fuzhou University, Fuzhou 350002 (People's Republic of China)
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  • The work was supported by the National Natural Science Foundation of China (grant numbers 20977016 and 21033003), the Program for Changjiang Scholars and Innovative Research Team in University (grant number PCSIRT0818). The Award Program for Minjiang Scholar Professorship and the NSF of Fujian province for Distinguished Young Investigator Grant (grant number 2009J06004) for Z. Li is also acknowledged.

Abstract

original image

Aus UV wird sichtbar: Die photokatalytische Reduktion von CO2 zu Formiat wurde erstmals mit sichtbarem Licht erreicht. Als Photokatalysator diente eine photoaktive titanhaltige Metall-organische Gerüstverbindung, die durch eine einfache Ligandensubstitution in dem auf UV-Licht reagierenden MIL-125(Ti)-Material erhalten wurde (siehe Schema; TEOA=Triethanolamin).

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