Zuschrift

Ruthenium/C5Me5/Bisphosphine- or Bisphosphite-Based Catalysts for normal-Selective Hydroformylation†

  1. Kohei Takahashi1,
  2. Dr. Makoto Yamashita1,3,*,
  3. Dr. Yoshiyuki Tanaka2,
  4. Prof. Dr. Kyoko Nozaki1,*

Article first published online: 21 MAR 2012

DOI: 10.1002/ange.201108396

Issue

Angewandte Chemie

Angewandte Chemie

Volume 124, Issue 18, pages 4459–4463, April 27, 2012

Additional Information

How to Cite

Takahashi, K., Yamashita, M., Tanaka, Y. and Nozaki, K. (2012), Ruthenium/C5Me5/Bisphosphine- or Bisphosphite-Based Catalysts for normal-Selective Hydroformylation . Angew. Chem., 124: 4459–4463. doi: 10.1002/ange.201108396

Author Information

  1. 1

    Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku 113-8656, Tokyo (Japan) http://park.itc.u-tokyo.ac.jp/nozakilab/

  2. 2

    Mitsubishi Chemical Corporation, Mizushima R&D Center, 3-10 Ushiodori, Kurashiki, 712-8054, Okayama (Japan)

  3. 3

    Current address: Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University, Tokyo (Japan)

*Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku 113-8656, Tokyo (Japan) http://park.itc.u-tokyo.ac.jp/nozakilab/

  1. †

    K.N. is grateful to Prof. Charles P. Casey (Univ. of Wisconsin) for helpful discussions. K.T. acknowledges a JSPS research fellowship. This work was supported by Funding Program for Next Generation World-Leading Researchers, Green Innovation, JSPS.

Publication History

  1. Issue published online: 24 APR 2012
  2. Article first published online: 21 MAR 2012
  3. Manuscript Revised: 18 JAN 2012
  4. Manuscript Received: 29 NOV 2011

Funded by

  • JSPS

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Keywords:

  • Aldehyde;
  • Cyclopentadienyl;
  • Hydroformylierungen;
  • Ruthenium;
  • Synthesemethoden
Thumbnail image of graphical abstract

Der Weg zur Normalität: In Gegenwart von [Cp*Ru]-Komplexen mit Bisphosphit- oder Bisphosphan-Liganden gelang die selektive Hydrofomylierung von Propen und 1-Decen zum verlängerten normal-Aldehyd mit den höchsten Aktivitäten und Selektivitäten, die für Rutheniumkatalysatoren beschrieben wurden (siehe Schema). Der Reaktionsmechanismus wurde durch Experimente mit stöchiometrischen Mengen an [Cp*Ru(Xantphos)H] und [D2]-1-Decen untersucht.

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