Self-Assembly of M24L48 Polyhedra Based on Empirical Prediction

Authors

  • Dr. Jens Bunzen,

    1. Department of Chemistry, NanoScience Center, University of Jyväskylä, P.O. Box 35, 40014 Jyväskylä (Finland)
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  • Junji Iwasa,

    1. Department of Applied Chemistry, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)
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  • Pia Bonakdarzadeh,

    1. Department of Chemistry, NanoScience Center, University of Jyväskylä, P.O. Box 35, 40014 Jyväskylä (Finland)
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  • Eri Numata,

    1. Department of Applied Chemistry, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)
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  • Prof. Kari Rissanen,

    Corresponding author
    1. Department of Chemistry, NanoScience Center, University of Jyväskylä, P.O. Box 35, 40014 Jyväskylä (Finland)
    • Department of Chemistry, NanoScience Center, University of Jyväskylä, P.O. Box 35, 40014 Jyväskylä (Finland)
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  • Dr. Sota Sato,

    Corresponding author
    1. Department of Applied Chemistry, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)
    • Department of Applied Chemistry, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)
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  • Prof. Makoto Fujita

    Corresponding author
    1. Department of Applied Chemistry, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)
    • Department of Applied Chemistry, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)
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  • This work was supported by KAKENHI (MEXT), the Strategic Japanese–Finnish Cooperative Program (JST-Academy of Finland), and The Academy of Finland. The synchrotron X-ray experiments were performed at AS, KEK, and SPring-8.

Abstract

original image

Entschiedener Übergang: Ein kleiner Unterschied im Winkel eines zweizähnigen Liganden (siehe Schema) führt zur Bildung inkommensurabler Komplexstrukturen (M12L24 und M24L48). Der M12L24/M24L48-Wechsel wurde aus dem empirischen Grenzwert des Ligandwinkels vorhergesagt, der durch ein Ligandenmischexperiment bestimmt wurde.

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