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On Demand: The Singular rht Net, an Ideal Blueprint for the Construction of a Metal–Organic Framework (MOF) Platform

Authors

  • Dr. Jarrod F. Eubank,

    1. Department of Chemistry, University of South Florida, 4202 East Fowler Avenue (CHE 205), Tampa, FL 33620 (USA)
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    • These authors contributed equally to this work.

  • Dr. Farid Nouar,

    1. Department of Chemistry, University of South Florida, 4202 East Fowler Avenue (CHE 205), Tampa, FL 33620 (USA)
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    • These authors contributed equally to this work.

  • Ryan Luebke,

    1. KAUST Advanced Membranes & Porous Materials Center, King Abdullah University of Science and Technology, 4700 King Abdullah University of Science and Technology, Thuwal 23955-6900 (Kingdom of Saudi Arabia)
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  • Dr. Amy J. Cairns,

    1. KAUST Advanced Membranes & Porous Materials Center, King Abdullah University of Science and Technology, 4700 King Abdullah University of Science and Technology, Thuwal 23955-6900 (Kingdom of Saudi Arabia)
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  • Dr. Lukasz Wojtas,

    1. Department of Chemistry, University of South Florida, 4202 East Fowler Avenue (CHE 205), Tampa, FL 33620 (USA)
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  • Dr. Mohamed Alkordi,

    1. KAUST Advanced Membranes & Porous Materials Center, King Abdullah University of Science and Technology, 4700 King Abdullah University of Science and Technology, Thuwal 23955-6900 (Kingdom of Saudi Arabia)
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  • Dr. Till Bousquet,

    1. Department of Chemistry, University of South Florida, 4202 East Fowler Avenue (CHE 205), Tampa, FL 33620 (USA)
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  • Matthew R. Hight,

    1. Department of Chemistry, University of South Florida, 4202 East Fowler Avenue (CHE 205), Tampa, FL 33620 (USA)
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  • Dr. Juergen Eckert,

    1. Department of Chemistry, University of South Florida, 4202 East Fowler Avenue (CHE 205), Tampa, FL 33620 (USA)
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  • Dr. Jan P. Embs,

    1. Laboratory for Neutron Scattering, Paul Scherrer Institut (Switzerland)
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  • Dr. Peter A. Georgiev,

    1. Department of Structural Chemistry, University of Milan (Italy)
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  • Prof. Dr. Mohamed Eddaoudi

    Corresponding author
    1. KAUST Advanced Membranes & Porous Materials Center, King Abdullah University of Science and Technology, 4700 King Abdullah University of Science and Technology, Thuwal 23955-6900 (Kingdom of Saudi Arabia)
    2. Department of Chemistry, University of South Florida, 4202 East Fowler Avenue (CHE 205), Tampa, FL 33620 (USA)
    • KAUST Advanced Membranes & Porous Materials Center, King Abdullah University of Science and Technology, 4700 King Abdullah University of Science and Technology, Thuwal 23955-6900 (Kingdom of Saudi Arabia)
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  • We gratefully acknowledge the financial support of the NSF (DMR 0548117) and KAUST funds.

Abstract

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Dank ihres außergewöhnlichen Charakters ist die rht-MOF-Plattform, die auf dem einzigen Netz beruht, das 3- und 24-fach verknüpfte Knoten aufweist, ein ideales Ziel für die Kristallchemie. Die auf diese Weise mögliche Kontrolle deutet auf einen beispiellosen Weg zu isoretikulären funktionellen Materialien für bestimmte Anwendungen hin, wobei keine Durchdringung befürchtet werden muss.

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