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Fullerene Doping: Preparation of Azafullerene C59NH and Oxafulleroids C59O3 and C60O4

Authors

  • Nana Xin,

    1. Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of the Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China)
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  • Huan Huang,

    1. Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of the Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China)
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  • Dr. Jianxin Zhang,

    1. Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of the Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China)
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  • Zhifei Dai,

    1. Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of the Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China)
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  • Prof. Dr. Liangbing Gan

    Corresponding author
    1. Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of the Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China)
    2. Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032 (China)
    • Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of the Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China)
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  • Financial support is provided by NNSFC (Nos. 20972003, 21132007) and MOST (No. 2011CB808401).

Abstract

original image

Fullerenoberflächen im Wandel: Der Austausch eines Kohlenstoffatoms im Fullerenkäfig gegen ein Stickstoff- oder Sauerstoffatom gelingt unter Beteiligung von Fullerenperoxid. Auf ähnliche Weise sind Oxafulleroide zugänglich, in denen mehrere Sauerstoffatome in das Käfiggerüst eingefügt sind. Das Dioxafulleren C58O2 wurde unter MALDI-TOF-Bedingungen selektiv in der Gasphase erzeugt.

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