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Structure and Reactivity of an Iodosylarene Adduct of a Manganese(IV)–Salen Complex

Authors

  • Chunlan Wang,

    1. Institute for Molecular Science and Okazaki Institute for Integrative Bioscience, National Institutes of Natural Sciences and Department of Functional Molecular Science, The Graduate University for Advanced Studies (SOKENDAI), Myodaiji, Okazaki 444-8787 (Japan)
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  • Dr. Takuya Kurahashi,

    1. Institute for Molecular Science and Okazaki Institute for Integrative Bioscience, National Institutes of Natural Sciences and Department of Functional Molecular Science, The Graduate University for Advanced Studies (SOKENDAI), Myodaiji, Okazaki 444-8787 (Japan)
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  • Prof. Dr. Hiroshi Fujii

    Corresponding author
    1. Institute for Molecular Science and Okazaki Institute for Integrative Bioscience, National Institutes of Natural Sciences and Department of Functional Molecular Science, The Graduate University for Advanced Studies (SOKENDAI), Myodaiji, Okazaki 444-8787 (Japan)
    • Institute for Molecular Science and Okazaki Institute for Integrative Bioscience, National Institutes of Natural Sciences and Department of Functional Molecular Science, The Graduate University for Advanced Studies (SOKENDAI), Myodaiji, Okazaki 444-8787 (Japan)
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  • This work was supported by grants from the Japan Society for the Promotion of Science (Grant-in-Aid for Scientific Research, Grant No. 22350030 and 23550086).

Abstract

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O-Transfer: Die Kristallstruktur eines Addukts aus Iodosylaren und einem Mangan(IV)-Salen-Komplex zeigt eine Bis(iodosylaren)-Koordination mit einer gestuften Konformation des Salenliganden. Die spektroskopische Charakterisierung deutet darauf hin, dass der Komplex die Struktur auch in Lösung beibehält. Eine Reaktivitätsstudie belegt, das Mangan-gebundenes Iodosylaren ein Sauerstoffatom direkt auf ein Substrat übertragen kann.

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