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Spectroscopic Evidence for the Structure Directing Role of the Solvent in the Synthesis of Two Iron Carboxylates

Authors

  • Tadeja Birsa Čelič,

    1. Laboratory for Inorganic Chemistry and Technology, National Institute of Chemistry, Hajdrihova 19, 1000 Ljubljana (Slovenia)
    2. Centre of Excellence Low Carbon Technologies, Hajdrihova 19, 1000 Ljubljana (Slovenia)
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  • Dr. Mojca Rangus,

    1. Laboratory for Inorganic Chemistry and Technology, National Institute of Chemistry, Hajdrihova 19, 1000 Ljubljana (Slovenia)
    2. Centre of Excellence Low Carbon Technologies, Hajdrihova 19, 1000 Ljubljana (Slovenia)
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  • Dr. Károly Lázár,

    1. Centre for Energy Research, Institute of Isotopes, HAS, P.O. Box 77, 1525 Budapest (Hungary)
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  • Prof. Venčeslav Kaučič,

    1. Laboratory for Inorganic Chemistry and Technology, National Institute of Chemistry, Hajdrihova 19, 1000 Ljubljana (Slovenia)
    2. Centre of Excellence Low Carbon Technologies, Hajdrihova 19, 1000 Ljubljana (Slovenia)
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  • Prof. Nataša Zabukovec Logar

    Corresponding author
    1. Laboratory for Inorganic Chemistry and Technology, National Institute of Chemistry, Hajdrihova 19, 1000 Ljubljana (Slovenia)
    2. Centre of Excellence Low Carbon Technologies, Hajdrihova 19, 1000 Ljubljana (Slovenia)
    • Laboratory for Inorganic Chemistry and Technology, National Institute of Chemistry, Hajdrihova 19, 1000 Ljubljana (Slovenia)
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  • This work was supported by the Slovenian Research Agency research programme P1-0021, Sloveninan-Hungarian bilateral project TÉT_10-1-2011-0624, DESY, and the EU FP7/2007-2013 programme ELISA (grant number 226716). Access to SR facilities of ELETTRA (project number 20105073) and HASYLAB (project II-20080058 EC), and collaboration with Prof. Iztok Arčon is acknowledged.

Abstract

original image

Kristall-Engineering: Die Synthese der Metall-organischen Gerüstverbindungen MIL-100(Fe) und MIL-45(Fe) wurde spektroskopisch untersucht. Die Produkte wurden unter identischen Bedingungen durch Wechsel des Lösungsmittels von reinem Wasser zu einer Mischung aus Wasser und Aceton erhalten. Die Ausgangslösung, das Gel und das Endprodukt der Reaktion wurden mit Röntgenabsorptionsspektroskopie charakterisiert (siehe Bild).

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