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A Remarkable Organometallic Transformation on a Cage-Incarcerated Dinuclear Ruthenium Complex

Authors

  • Shinnosuke Horiuchi,

    1. Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)
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  • Dr. Takashi Murase,

    1. Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)
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  • Prof. Dr. Makoto Fujita

    Corresponding author
    1. Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)
    • Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)
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Errata

This article is corrected by:

  1. Errata: Berichtigung: A Remarkable Organometallic Transformation on a Cage-Incarcerated Dinuclear Ruthenium Complex Volume 125, Issue 8, 2201, Article first published online: 13 February 2013

  • This research was supported by the CREST project of the Japan Science and Technology Agency (JST) and KAKENHI (24000009), MEXT (Japan).

Abstract

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Unter Verschluss: Die Photosubstitution eines CO-Liganden durch ein Alkin auf einem zweikernigen Ru-Carbonyl-Komplex in einem selbstorganisierten Käfig verläuft ohne Spaltung der photolabilen Ru-Ru-Bindung. Der resultierende Ru-Alkin-π-Komplex ist ein Reaktionsintermediat, das im Käfig stabilisiert wird. Außerhalb des Käfigs kann der π-Komplex durch intramolekulare CO-Insertion weiter zu einem Diruthenacyclopentenon reagieren (siehe Schema).

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