SEARCH

SEARCH BY CITATION

Keywords:

  • Allylamine;
  • Arine;
  • Aza-Claisen-Umlagerungen;
  • Mittlere Ringe

Den Verbindungen 14 a, 14 b und 14 c ist in Tabelle 3 dieser Zuschrift fälschlicherweise die E-Doppelbindungskonfiguration zugewiesen. Die korrekte Konfiguration ist Z, wie hier in der korrigierten Tabelle gezeigt. Diese Berichtigung wird ergänzt durch eine revidierte Hintergrundinformation.

Table 3. Synthesis of medium-ring amines using the benzyne aza-Claisen rearrangment.[a]inline image
EntryAmineProductYield [%][b]
  1. [a] Reaction conditions: o-trimethylsilylphenyl triflate (1 equiv), amine (1.5 equiv), and CsF (3 equiv) in toluene (0.75 mL) and MeCN (0.25 mL). Reactions were carried out on a 0.2 mmol scale and were stirred for 24 hours at room temperature and then heated at reflux for 48 hours in a sealed tube. [b] Yield of isolated product. [c] 2 equivalents of o-trimethylsilylphenyl triflate to 1 equivalent of amine was used. Bn= benzyl.

1
Thumbnail image of
13 a
Thumbnail image of
14 a41
2[c]
Thumbnail image of
13 b
Thumbnail image of
14 b40
3
Thumbnail image of
13 c
Thumbnail image of
14 c28

Die Autoren entschuldigen sich für dieses Versehen.

Supporting Information

  1. Top of page
  2. Supporting Information

Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors.

FilenameFormatSizeDescription
ange_201206624_sm_miscellaneous_information.pdf1478Kmiscellaneous_information

Please note: Wiley Blackwell is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.