Get access
Advertisement

Transition-Metal-Free Aerobic Oxidative Cleavage of C[BOND]C Bonds in α-Hydroxy Ketones and Mechanistic Insight to the Reaction Pathway

Authors

  • Hui Liu,

    1. Shanghai Key Laboratory of Green Chemistry and Chemical Process, Department of Chemistry, East China Normal University, 3663 North Zhongshan Road, Shanghai 200062 (P. R. China)
    Search for more papers by this author
  • Chao Dong,

    1. Shanghai Key Laboratory of Green Chemistry and Chemical Process, Department of Chemistry, East China Normal University, 3663 North Zhongshan Road, Shanghai 200062 (P. R. China)
    Search for more papers by this author
  • Zeguang Zhang,

    1. Shanghai Key Laboratory of Green Chemistry and Chemical Process, Department of Chemistry, East China Normal University, 3663 North Zhongshan Road, Shanghai 200062 (P. R. China)
    Search for more papers by this author
  • Peiyu Wu,

    1. Shanghai Key Laboratory of Green Chemistry and Chemical Process, Department of Chemistry, East China Normal University, 3663 North Zhongshan Road, Shanghai 200062 (P. R. China)
    Search for more papers by this author
  • Prof. Dr. Xuefeng Jiang

    Corresponding author
    1. Shanghai Key Laboratory of Green Chemistry and Chemical Process, Department of Chemistry, East China Normal University, 3663 North Zhongshan Road, Shanghai 200062 (P. R. China)
    • Shanghai Key Laboratory of Green Chemistry and Chemical Process, Department of Chemistry, East China Normal University, 3663 North Zhongshan Road, Shanghai 200062 (P. R. China)
    Search for more papers by this author

  • Financial support was provided by the NSFC (21272075), the “Yingcai Program” of ECNU, the “Shanghai Pujiang Program” (12J1402500), and “Shanghai Talent Development Support” (2011022).

Abstract

original image

Klarer Schnitt: Für die Titelreaktion wurde O2, das ideale Oxidans, als einziges Oxitationsmittel verwendet. Das Dimerintermediat (siehe Schema) und Isotopenmarkierungsexperimente mit 18O2 konnten teilweise den Reaktionsmechanismus aufklären.

Get access to the full text of this article

Ancillary