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The Inherent Single-Molecule Magnet Character of Trivalent Uranium

Authors

  • Dr. Fabrizio Moro,

    1. School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD (UK)
    2. Current address: School of Chemistry, The University of Manchester, Oxford Road, Manchester M13 9PL (UK)
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  • Dr. David P. Mills,

    1. School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD (UK)
    2. Current address: School of Chemistry, The University of Manchester, Oxford Road, Manchester M13 9PL (UK)
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  • Dr. Stephen T. Liddle,

    Corresponding author
    1. School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD (UK)
    • School of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD (UK)
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  • Prof. Dr. Joris van Slageren

    Corresponding author
    1. Institut für Physikalische Chemie, Universität Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart (Germany)
    • Institut für Physikalische Chemie, Universität Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart (Germany)
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  • We thank the Royal Society, the Engineering and Physical Sciences Research Council, the Deutsche Forschungsgemeinschaft, the European Research Council, the European Union (grant number IEF 253980 to F.M.), the University of Nottingham, COST Action CM1006, and the UK National Nuclear Laboratory for generously funding this work.

Abstract

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Uran-Magnete: Drei Uran(III)-Komplexe mit deutlich verschiedenen Strukturen und Zusammensetzungen zeigen eine langsame Relaxation der Magnetisierung. Die Studie erweitert das Spektrum langsam relaxierender Uran-Komplexe und zeigt, dass dieses Verhalten nicht auf spezielle Ligandentypen oder molekulare Symmetrien beschränkt ist (siehe Bild).

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