Get access

Direct Annulations toward Phosphorylated Oxindoles: Silver-Catalyzed Carbon-Phosphorus Functionalization of Alkenes

Authors

  • Ya-Min Li,

    1. State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000 (P. R. China)
    Search for more papers by this author
  • Meng Sun,

    1. State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000 (P. R. China)
    Search for more papers by this author
  • Hong-Li Wang,

    1. State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000 (P. R. China)
    Search for more papers by this author
  • Qiu-Ping Tian,

    1. State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000 (P. R. China)
    Search for more papers by this author
  • Prof. Shang-Dong Yang

    Corresponding author
    1. State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000 (P. R. China)
    2. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Lanzhou 730000 (P. R. China)
    • State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000 (P. R. China)
    Search for more papers by this author

  • We are grateful to the NSFC (Nos. 21272100), Program for Changjiang Scholars and Innovative Research Team in University (PCSIRT: IRT1138), and Research Fund for the Doctoral Program of Higher Education of China (Nos. 20100211120014) for financial support. We thank S. F. Reichard, MA for editing the manuscript.

Abstract

original image

Silberstreif: Die AgNO3-katalysierte Kohlenstoffphosphorylierung von Alkenen verläuft über eine Additions-Cyclisierungs-Kaskade. Ag+ reagiert mit Ph2P(O)H zur aktiven Zwischenstufe 1, die die Reaktion katalysiert. Die Methode benötigt lediglich ein preiswertes ungiftiges Silbersalz als Katalysator und ist auf einfache, leicht zugängliche Substrate anwendbar.

Ancillary