Azaborine Compounds for Organic Field-Effect Transistors: Efficient Synthesis, Remarkable Stability, and BN Dipole Interactions

Authors

  • Xiao-Ye Wang,

    1. Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (P. R. China)
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  • Hao-Ran Lin,

    1. Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (P. R. China)
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  • Ting Lei,

    1. Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (P. R. China)
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  • Dong-Chu Yang,

    1. Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (P. R. China)
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  • Fang-Dong Zhuang,

    1. Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (P. R. China)
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  • Dr. Jie-Yu Wang,

    Corresponding author
    1. Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (P. R. China)
    • Jie-Yu Wang, Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (P. R. China)

      Si-Chun Yuan, Department of Fundamental Science, Beijing University of Agriculture, Beijing 102206 (P. R. China)

      Jian Pei, Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (P. R. China)

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  • Prof. Si-Chun Yuan,

    Corresponding author
    1. Department of Fundamental Science, Beijing University of Agriculture, Beijing 102206 (P. R. China)
    • Jie-Yu Wang, Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (P. R. China)

      Si-Chun Yuan, Department of Fundamental Science, Beijing University of Agriculture, Beijing 102206 (P. R. China)

      Jian Pei, Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (P. R. China)

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  • Prof. Jian Pei

    Corresponding author
    1. Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (P. R. China)
    • Jie-Yu Wang, Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (P. R. China)

      Si-Chun Yuan, Department of Fundamental Science, Beijing University of Agriculture, Beijing 102206 (P. R. China)

      Jian Pei, Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (P. R. China)

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  • This work was supported by the Major State Basic Research Development Program (grant numbers 2009CB623601 and 2013CB933501) from the Ministry of Science and Technology and the National Natural Science Foundation of China. The authors thank Prof. Xiao-Yu Cao from Xiamen University for helpful discussions.

Abstract

original image

Bor-Stickstoff-Einheiten wurden in Thiophen-haltige polycyclische aromatische Verbindungen eingebaut. Auf diesen Azaborinen basierende organische Feldeffekt-Transistoren wurden hergestellt, die ein neues Entwicklungskonzept für organische Halbleiter zeigen und für eine breite Klasse von BN-haltigen Verbindungen die Chance auf eine Anwendung in künftigen organischen elektronischen Geräten bieten (siehe Bild; μFET=Lochbeweglichkeit).

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