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Bio-Inspired Catalytic Imine Reduction by Rhodium Complexes with Tethered Hantzsch Pyridinium Groups: Evidence for Direct Hydride Transfer from Dihydropyridine to Metal-Activated Substrate†

  1. Alex McSkimming1,
  2. Dr. Mohan M. Bhadbhade2,
  3. Prof. Stephen B. Colbran1,*

Article first published online: 26 FEB 2013

DOI: 10.1002/ange.201210086

Issue

Angewandte Chemie

Angewandte Chemie

Volume 125, Issue 12, pages 3495–3500, March 18, 2013

Additional Information

How to Cite

McSkimming, A., Bhadbhade, M. M. and Colbran, S. B. (2013), Bio-Inspired Catalytic Imine Reduction by Rhodium Complexes with Tethered Hantzsch Pyridinium Groups: Evidence for Direct Hydride Transfer from Dihydropyridine to Metal-Activated Substrate . Angew. Chem., 125: 3495–3500. doi: 10.1002/ange.201210086

Author Information

  1. 1

    School of Chemistry, University of New South Wales, Sydney, NSW 2052 (Australia)

  2. 2

    Mark Wainwright Analytical Centre, University of New South Wales, Sydney, NSW 2052 (Australia)

*School of Chemistry, University of New South Wales, Sydney, NSW 2052 (Australia)

  1. †

    This work was supported by ARC Discovery Projects (DP1301033514). We thank the Australian Synchrotron for access to crystallography facilities.

Publication History

  1. Issue published online: 20 MAR 2013
  2. Article first published online: 26 FEB 2013
  3. Manuscript Received: 18 DEC 2012

Funded by

  • ARC Discovery Projects. Grant Number: DP1301033514

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View Full Article with Supporting Information (HTML) Get PDF (568K)