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Multiple Lanthanide Helicate Clusters and the Effects of Anions on Their Configuration

Authors

  • Bei Wang,

    1. Key Laboratory of Nonferrous Metals Chemistry and Resources Utilization of Gansu Province, State Key Laboratory of Applied Organic Chemistry, and College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000 (P.R. China)
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  • Dr. Zhipeng Zang,

    1. Key Laboratory of Nonferrous Metals Chemistry and Resources Utilization of Gansu Province, State Key Laboratory of Applied Organic Chemistry, and College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000 (P.R. China)
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  • Haihong Wang,

    1. Key Laboratory of Nonferrous Metals Chemistry and Resources Utilization of Gansu Province, State Key Laboratory of Applied Organic Chemistry, and College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000 (P.R. China)
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  • Dr. Wei Dou,

    1. Key Laboratory of Nonferrous Metals Chemistry and Resources Utilization of Gansu Province, State Key Laboratory of Applied Organic Chemistry, and College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000 (P.R. China)
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  • Dr. Xiaoliang Tang,

    1. Key Laboratory of Nonferrous Metals Chemistry and Resources Utilization of Gansu Province, State Key Laboratory of Applied Organic Chemistry, and College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000 (P.R. China)
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  • Prof. Weisheng Liu,

    Corresponding author
    1. Key Laboratory of Nonferrous Metals Chemistry and Resources Utilization of Gansu Province, State Key Laboratory of Applied Organic Chemistry, and College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000 (P.R. China)
    • Key Laboratory of Nonferrous Metals Chemistry and Resources Utilization of Gansu Province, State Key Laboratory of Applied Organic Chemistry, and College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000 (P.R. China)===

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  • Yongliang Shao,

    1. Key Laboratory of Nonferrous Metals Chemistry and Resources Utilization of Gansu Province, State Key Laboratory of Applied Organic Chemistry, and College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000 (P.R. China)
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  • Dr. Jingxin Ma,

    1. College of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021 (P. R. China)
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  • Prof. Dr. Yizhi Li,

    1. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093 (P.R. China)
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  • Dr. Jiang Zhou

    1. Analytical Instrumentation Center, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (P.R. China)
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  • The authors acknowledge financial support from the NSFC (20931003, and 91122007) and the Specialized Research Fund for the Doctoral Program of Higher Education (20110211130002).

Abstract

original image

Forme Dir Deinen Cluster: Zwei supramolekulare Cluster aus Lanthanoidhelicaten wurden synthetisiert. Die Clusterstruktur hängt von der Wahl des Anions ab: tetraedrisches ClO4 ergibt größere ringförmige Helicate, während trigonal-planares NO3 zu einem kompakten viersträngigen Helicat führt (siehe Bild).

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