Iron-Catalyzed, Atom-Economical, Chemo- and Regioselective Alkene Hydroboration with Pinacolborane

Authors

  • Lei Zhang,

    1. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, 345 Lingling Road, Shanghai 200032 (China)
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  • Dongjie Peng,

    1. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, 345 Lingling Road, Shanghai 200032 (China)
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  • Dr. Xuebing Leng,

    1. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, 345 Lingling Road, Shanghai 200032 (China)
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  • Prof. Dr. Zheng Huang

    Corresponding author
    1. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, 345 Lingling Road, Shanghai 200032 (China)
    • State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, 345 Lingling Road, Shanghai 200032 (China)===

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  • We gratefully acknowledge financial support from the National Natural Sciences Foundation of China (21272255, 21121062), the “1000 Youth Talents Plan”, and the Chinese Academy of Sciences.

Abstract

original image

Edles Eisen: Ein Eisenkomplex mit P,N,N-Ligand für katalytische Alkenhydroborierungen unter milden Bedingungen wurde entwickelt. Das System mit dem umweltverträglichen und leicht verfügbaren Katalysatormetall ist Edelmetallsystemen bei α-Olefin-Hydroborierungen mit Pinakolboran hinsichtlich Effizienz und Selektivität überlegen.

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