A Base-Stabilized Lead(I) Dimer and an Aromatic Plumbylidenide Anion

Authors

  • Siew-Peng Chia,

    1. Division of Chemistry and Biological Chemistry, Nanyang Technological University, 21 Nanyang Link, Singapore 637371 (Singapore)
    Search for more papers by this author
  • Dr. Hong-Wei Xi,

    1. Division of Chemical and Biomolecular Engineering, Nanyang Technological University, 62 Nanyang Drive, Singapore 637459 (Singapore)
    Search for more papers by this author
  • Dr. Yongxin Li,

    1. Division of Chemistry and Biological Chemistry, Nanyang Technological University, 21 Nanyang Link, Singapore 637371 (Singapore)
    Search for more papers by this author
  • Prof. Dr. Kok Hwa Lim,

    1. Division of Chemical and Biomolecular Engineering, Nanyang Technological University, 62 Nanyang Drive, Singapore 637459 (Singapore)
    Search for more papers by this author
  • Dr. Cheuk-Wai So

    Corresponding author
    1. Division of Chemistry and Biological Chemistry, Nanyang Technological University, 21 Nanyang Link, Singapore 637371 (Singapore)
    • Division of Chemistry and Biological Chemistry, Nanyang Technological University, 21 Nanyang Link, Singapore 637371 (Singapore)

    Search for more papers by this author

  • This work is supported by the Central Strategic Initiative for Inter-disciplinary Competitive Fund.

Abstract

original image

Aromatische niedervalente Blei-Analoga eines Indenylanions (siehe Schema; 1) werden durch SnCl2 unter Bildung des basestabilisierten Blei(I)-Dimers 2 oxidiert. Die Reduktion von 2 mit Lithium führt wieder zu 1. Beide Spezies wurden NMR-spektroskopisch und Röntgen- kristallographisch charakterisiert.

Ancillary