Get access

Palladium-Induced Pyrrolic Rearrangement of a Singly to a Doubly N-Confused [26]Hexaphyrin

Authors

  • Dr. Sabapathi Gokulnath,

    1. Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Fukuoka 819-0395 (Japan)
    Search for more papers by this author
  • Keiichi Nishimura,

    1. Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Fukuoka 819-0395 (Japan)
    Search for more papers by this author
  • Dr. Motoki Toganoh,

    1. Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Fukuoka 819-0395 (Japan)
    Search for more papers by this author
  • Dr. Shigeki Mori,

    1. Department of Molecular Science, Integrated Center for Science, Ehime University, Matsuyama 790-8577 (Japan)
    Search for more papers by this author
  • Prof. Dr. Hiroyuki Furuta

    Corresponding author
    1. Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Fukuoka 819-0395 (Japan)
    2. International Research Center for Molecular Systems, Kyushu University, Fukuoka 819-0395 (Japan)
    • Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Fukuoka 819-0395 (Japan)

    Search for more papers by this author

  • The present work was supported by a Grant-in-Aid for Scientific Research (22350020 and 23108715) from the Ministry of Education, Culture, Sports, Science and Technology of Japan.

Abstract

original image

Eine Pyrrol-Umlagerung überführt ein einfach N-verdrehtes [26]Hexaphyrin unter Einwirkung von PdCl2 in den Dipalladium(II)-Komplex eines doppelt N-verdrehten [26]Hexaphyrins. Dieser Komplex ist eines von wenigen Beispielen für aromatische Verbindungen mit definiertem nichtentartetem HOMO und LUMO.

Get access to the full text of this article

Ancillary