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Boracyclophanes: Modulation of the σ/π Character in Boron–Benzene Interactions

Authors

  • Tomokatsu Kushida,

    1. Institute of Transformative Bio-Molecules (WPI-ITbM), Research Center for Materials Science, and Graduate School of Science, Nagoya University, Furo, Chikusa, Nagoya 464-8602 (Japan)
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  • Prof. Dr. Shigehiro Yamaguchi

    Corresponding author
    1. Institute of Transformative Bio-Molecules (WPI-ITbM), Research Center for Materials Science, and Graduate School of Science, Nagoya University, Furo, Chikusa, Nagoya 464-8602 (Japan)
    • Institute of Transformative Bio-Molecules (WPI-ITbM), Research Center for Materials Science, and Graduate School of Science, Nagoya University, Furo, Chikusa, Nagoya 464-8602 (Japan)
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  • This work was partly supported by CREST, JST, and a Grant-in-Aid for Scientific Research on Innovative Areas (Stimuli-responsive Chemical Species, No. 24109007) from the Ministry of Education, Culture, Sports, Science, and Technology of Japan. T.K. thanks the JSPS Research Fellowship for Young Scientists.

Abstract

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Charakterzeichnung: Boracyclophane, in denen der Benzolring an das Boratom koordiniert, wurden synthetisiert. Die Eigenschaften der Bor-Benzol-Wechselwirkung wurden in Röntgenstrukturanalysen und theoretischen Studien aufgeklärt. Der σ/π-Charakter der Wechselwirkung kann über die Elektronendonoreigenschaften des Benzolrings moduliert werden.

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