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Enhanced Reactivity of a Biomimetic Iron(II) α-Keto Acid Complex through Immobilization on Functionalized Gold Nanoparticles

Authors

  • Debobrata Sheet,

    1. Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, 2A & 2B Raja S. C. Mullick Road, Jadavpur, Kolkata-700032 (India)
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  • Dr. Partha Halder,

    1. Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, 2A & 2B Raja S. C. Mullick Road, Jadavpur, Kolkata-700032 (India)
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  • Dr. Tapan Kanti Paine

    Corresponding author
    1. Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, 2A & 2B Raja S. C. Mullick Road, Jadavpur, Kolkata-700032 (India)
    • Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, 2A & 2B Raja S. C. Mullick Road, Jadavpur, Kolkata-700032 (India)===

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  • T.K.P. acknowledges the DST, Govt. of India (Project SR/S1/IC-51/2010) for financial support. D.S. thanks CSIR, India, for a fellowship.

Abstract

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Immobilisierter biomimetischer Eisenkomplex: Ein Eisen(II)-Benzoylformiatkomplex wurde über einen Thiol-substituierten N4-Liganden an Goldnanopartikeln immobilisiert. Der Komplex aktiviert Disauerstoff und katalysiert die oxidative Decarboxylierung von Benzoylameisensäure zu Benzoesäure.

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