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Permanent Porosity Derived From the Self-Assembly of Highly Luminescent Molecular Zinc Carbonate Nanoclusters

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  • The authors acknowledge the Foundation for Polish Science Team Programme co-financed by the EU “European Regional Development Fund” TEAM/2011–7/8 and the National Science Centre (DEC-2011/01/B/ST5/06338) for financial support and the Royal Society (UK) for a University Research Fellowship (D.F.J.). K.S., I.J., and M.S. thank the NanOtechnology, Biomaterials and aLternative Energy Source for ERA integration (REGPOT-CT-2011-285949-NOBLESSE) Project from the EU. S.Y. gratefully acknowledges the receipt of a Leverhulme Trust Early Career Research Fellowship, and M.S. the receipt of an ERC Advanced Grant and EPSRC Programme Grant. We are grateful to Diamond Light Source for access to the Beamline I11.

Abstract

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Gefräßige Mikroporen: Die Reaktion von [Zn43-OH)2(L)4(tBu)2] (LH=8-Hydroxychinolin) mit CO2 liefert einen Festkörper mit 3D-Mikroporenstruktur, in dem sphärische Zinkcarbonat-Nanocluster diamantartig gepackt sind. Die Verbindung verfügt über eine der größten Brunauer-Emmett-Teller-Oberflächen unter nichtkovalenten porösen Materialien und kann große Mengen an H2, CO2 und CH4 aufnehmen.

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