Syntheses of Thiocarbamates

Authors

  • Prof. Dr. W. Walter,

    1. Chemisches Staatsinstitut, Institut für organische Chemie der Universität, Papendamm 6, 2 Hamburg 13, (Germany)
    Search for more papers by this author
  • Dr. K.-D. Bode

    Corresponding author
    1. Chemisches Staatsinstitut, Institut für organische Chemie der Universität, Papendamm 6, 2 Hamburg 13, (Germany)
    Current affiliation:
    1. Farbenfabriken Bayer AG, Wissenschaftliches Hauptlaboratorium, 509 Leverkusen-Bayerwerk (Germany)
    • Chemisches Staatsinstitut, Institut für organische Chemie der Universität, Papendamm 6, 2 Hamburg 13, (Germany)
    Search for more papers by this author

Abstract

The methods suitable for the preparation of thiocarbamates are described and illustrated by examples and procedures. They are grouped under the following headings:

  • 1Addition of Alcohols and Thiols to Isothiocyanates
  • 2Thioacylation of Amines
    • (a)with chlorothioformates
    • (b)with O,S-diesters of dithiocarbonic acid
    • (c)with trithiocarbonates
  • 3Thioacylation of Alcohols, Phenols, and Thiols
    • (a)with thiocarbamoyl chlorides
    • (b)with N,N-dialkylmercaptochloroformimidium chlorides
    • (c)with N,N′-thiocarbonyldiimidazole
  • 4Reaction of Thiocyanates and Cyanates with Hydrogen Sulfide
  • 5Alkylation of Metal Dithiocarbamates
  • 6Additions to Thiocyanic Acid

Ancillary