SEARCH

SEARCH BY CITATION

Keywords:

  • Thiocarbamates;
  • Synthetic methods

Abstract

The methods suitable for the preparation of thiocarbamates are described and illustrated by examples and procedures. They are grouped under the following headings:

  • 1
    Addition of Alcohols and Thiols to Isothiocyanates
  • 2
    Thioacylation of Amines
    • (a)
      with chlorothioformates
    • (b)
      with O,S-diesters of dithiocarbonic acid
    • (c)
      with trithiocarbonates
  • 3
    Thioacylation of Alcohols, Phenols, and Thiols
    • (a)
      with thiocarbamoyl chlorides
    • (b)
      with N,N-dialkylmercaptochloroformimidium chlorides
    • (c)
      with N,N′-thiocarbonyldiimidazole
  • 4
    Reaction of Thiocyanates and Cyanates with Hydrogen Sulfide
  • 5
    Alkylation of Metal Dithiocarbamates
  • 6
    Additions to Thiocyanic Acid