The First Oxoferrate(III) Having a Ring Structure: Na14[Fe6O16]

Authors

  • Dipl.-Chem. Gerold Brachtel,

    1. Institut für Anorganische und Analytische Chemie der Universität, Heinrich-Buff-Ring 58, D-6300 Giessen (Germany)
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  • Prof. Dr. Rudolf Hoppe

    Corresponding author
    1. Institut für Anorganische und Analytische Chemie der Universität, Heinrich-Buff-Ring 58, D-6300 Giessen (Germany)
    • Institut für Anorganische und Analytische Chemie der Universität, Heinrich-Buff-Ring 58, D-6300 Giessen (Germany)
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  • Part of the Dissertation by G. Brachtel, Universität Giessen.

Abstract

original image

Twelve-membered rings with alternate iron and oxygen atoms occur in Na14[Fe6O16]. Fe is surrounded almost tetrahedrally by O, and along [010] two thirds of the FeO4 tetrahedra are coupled in the form of a “Dreier-Doppelkette”.

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