Phenyl(trimethylphosphonio)methanidyl, A Novel 3-Electron Bridge Ligand

Authors

  • Dr. Fritz R. Kreissl,

    Corresponding author
    1. Anorganisch-chemisches Institut der Technischen Universität, Arcisstrasse 21, D-8000 München 2 (Germany)
    • Anorganisch-chemisches Institut der Technischen Universität Arcisstrasse 21, D-8000 München 2 (Germany)
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  • Dipl.-Chem. Peter Friedrich,

    1. Anorganisch-chemisches Institut der Technischen Universität, Arcisstrasse 21, D-8000 München 2 (Germany)
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  • Dr. Tassilo L. Lindner,

    1. Anorganisch-chemisches Institut der Technischen Universität, Arcisstrasse 21, D-8000 München 2 (Germany)
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  • Doz. Dr. Gottfried Huttner

    1. Anorganisch-chemisches Institut der Technischen Universität, Arcisstrasse 21, D-8000 München 2 (Germany)
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  • This work was supported by the Deutsche Forschungsgemeinschaft.

Abstract

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The tungsten-rhenium complex(1) contains a metal-metal bond and a novel bridging ligand. The structure deduced from spectra ha been confirmed by X-ray structure analysis.

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