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Synthesis and Some Reactions of 1,1-Dimethyl-2,2-bis-(trimethylsilyl)-1-silaethene

Authors

  • Prof. Dr. Nils Wiberg,

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    1. Institut für Anorganische Chemie der Universität, Meiserstrasse 1, D-8000 München 2 (Germany)
    • Institut für Anorganische Chemie der Universität Meiserstrasse 1, D-8000 München 2 (Germany)
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  • Dipl.-Chem. Gerhard Preiner

    1. Institut für Anorganische Chemie der Universität, Meiserstrasse 1, D-8000 München 2 (Germany)
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  • Unsaturated Silicon Compounds, Part 1. Also Part 40 of Compounds of Silicon and its Group Homologs.—Part 39: N. Wiberg, G. Hübler, Z. Naturforsch. B31, 1317 (1976).

Abstract

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Compounds having Si[DOUBLE BOND]C double bonds of type (1) are now accessible by elimination reactions in organic solvents under very mild conditions. Only pyrolytic and photochemical processes were previously available.

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