N-Acyl-N′-arylsulfonyldiazenes; Detection and Use in the Synthesis of Amides

Authors

  • Dr. Hansjürgen Gölz,

    1. Institut für Organische Chemie, Biochemie und Isotopenforschung der Universität, Pfaffenwaldring 55, D-7000 Stuttgart 80 (Germany)
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  • Dr. Bernd Glatz,

    1. Institut für Organische Chemie, Biochemie und Isotopenforschung der Universität, Pfaffenwaldring 55, D-7000 Stuttgart 80 (Germany)
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  • Dr. Georges Haas,

    1. Ciba-Geigy AG, CH-4000 Basel (Switzerland)
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    • Formerly at Cornell University, Ithaca, N. Y.

  • Dr. Günter Helmchen,

    Corresponding author
    1. Institut für Organische Chemie, Biochemie und Isotopenforschung der Universität, Pfaffenwaldring 55, D-7000 Stuttgart 80 (Germany)
    • Institut für Organische Chemie, Biochemie und Isotopenforschung der Universität, Pfaffenwaldring 55, D-7000 Stuttgart 80 (Germany)
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  • Prof. Dr. Hans Muxfeldt

    1. Institut für Organische Chemie, Biochemie und Isotopenforschung der Universität, Pfaffenwaldring 55, D-7000 Stuttgart 80 (Germany)
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Abstract

original image

The synthesis of amides under oxidative conditions can be accomplished by means of the reaction sequence (1)(2)(3). The novel N-acyl-N′-arylsulfonyldiazenes (2) were detected inter alia by trapping reactions.

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