Dichloro(porphyrinato)molybdenum(IV)—Synthesis and Structure

Authors

  • Dipl.-Ing. Tharcis Diebold,

    Corresponding author
    1. Laboratoire de Cristallochimie associé au CNRS, Institut le Bel, Université Louis Pasteur 4, rue Blaise Pascal, 67070 Strasbourg (France)
    • Laboratoire de Cristallochimie associé au CNRS, Institut Le Bel, Université Louis Pasteur 4, rue Blaise Pascal, 67070 Strasbourg (France)
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  • Dr. Bernard Chevrier,

    1. Laboratoire de Cristallochimie associé au CNRS, Institut le Bel, Université Louis Pasteur 4, rue Blaise Pascal, 67070 Strasbourg (France)
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  • Prof. Dr. Raymond Weiss

    1. Laboratoire de Cristallochimie associé au CNRS, Institut le Bel, Université Louis Pasteur 4, rue Blaise Pascal, 67070 Strasbourg (France)
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Abstract

Two porphyrinato-molybdenum(IV)compounds without and Mo[DOUBLE BOND]O bond have now been synthesized and thoroughly characterized. The paramagnetic compounds should prove useful starting materials for the synthesis of other porphyrin complexes of low-valent Mo.

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