Orientation dependence of charge-transfer interactions, Part 14.—Part 13: H. A. Staab, C. P. Herz, Angew. Chem. 89, 839 (1977); Angew. Chem. Int. Ed. Engl. 16, 799 (1977).
Indirectly Transmitted Charge-Transfer Interactions: Multilayered [2.2] Paracyclophane Quinhydrones†
Article first published online: 22 DEC 2003
Copyright © 1977 by Verlag Chemie, GmbH, Germany
Angewandte Chemie International Edition in English
Volume 16, Issue 11, pages 801–803, November 1977
How to Cite
Staab, H. A., Zapf, U. and Gurke, A. (1977), Indirectly Transmitted Charge-Transfer Interactions: Multilayered [2.2] Paracyclophane Quinhydrones. Angew. Chem. Int. Ed. Engl., 16: 801–803. doi: 10.1002/anie.197708011
- Issue published online: 22 DEC 2003
- Article first published online: 22 DEC 2003
- Manuscript Received: 26 SEP 1977
[2.2] Paracyclophane quinhydrones with intercalated benzene rings have now been synthesized for the first time in the form of their methyl ethers (1) and (2). Their broad CT band must be due to an intramolecular CT transition; the charge is transmitted in “vertical conjugation” through the π-electron system of the benzene. Orientation dependence of the CT absorption as observed in simple donor-acceptor 2.2 paracyclophanes is almost completely absent.