Addition Compounds with Polymeric Chromium(II)-Schiff Base Complexes

Authors

  • Prof. Dr. Wolfgang Sawodny,

    Corresponding author
    1. Abteilung für Anorganische Chemie der Universität, Oberer Eselsberg, D-7900 Ulm (Germany)
    • Abteilung für Anorganische Chemie der Universität, Oberer Eselsberg, D-7900 Ulm (Germany)
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  • Dipl.-Chem. Manfred Riederer

    1. Abteilung für Anorganische Chemie der Universität, Oberer Eselsberg, D-7900 Ulm (Germany)
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Abstract

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Highly stable complexes of Schiff bases and chromium(II), palladium(II), or platinum(II) have now been synthesized. Such a complex is the Cr2+ compound (2a). It can form addition compounds with molecules such as CH3OH, pyridine, or cyclohexane. Complexes of type (2) containing Pd2+ or Pt2+ and R = e.g.[BOND](CH2)x[BOND], x = 2–8, 10, 12 are accessible from (1) and K2PdCl4 or K2PtCl4 in DMF/NaOAc. They can also intercalate organic molecules.

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