A Stable Acyclic Alkoxyhalosulfurane: Chlorotris(2,2,2-trifluoro-1-trifluoromethylethoxy)sulfurane

Authors

  • Dr. Gerd-Volker Röschenthaler

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    1. Lehrstuhl B für Anorganische Chemie der Technischen Universität, Pockelsstrasse 4, D-3300 Braunschweig (Germany)
    • Lehrstuhl B für Anorganische Chemie der Technischen Universität, Pockelsstrasse 4, D-3300 Braunschweig (Germany)
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  • This work was supported by the Deutsche Forschungsgemeinschaft.

Abstract

Alkoxysulfuranes—compounds containing a tetracoordinated sulfur(IV)atom—are important intermediates in synthetic organic chemistry. The first open-chain chloroalkoxysulfurance has now been prepared. Surprisingly, it is able to alkoxylate

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