Carbonyl Olefination with (Triphenylstannyl)methyllithium

Authors

  • Prof. Dr. Thomas Kauffmann,

    Corresponding author
    1. Organisch-chemisches Institut der Universität, Orléans-Ring 23, D-4400 Münster (Germany)
    • Organisch-chemisches Institut der Universität, Orléans-Ring 23, D-4400 Münster (Germany)
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  • Dipl.-Chem. Reinhard Kriegesmann,

    1. Organisch-chemisches Institut der Universität, Orléans-Ring 23, D-4400 Münster (Germany)
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  • Annegret Woltermann

    1. Organisch-chemisches Institut der Universität, Orléans-Ring 23, D-4400 Münster (Germany)
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  • New Reagents, Part 8.—This work was supported by the Ministerium für Wissenschaft und Forschung des Landes Nordrhein-Westfalen and the Fonds der Chemischen Industrie. Part 7: Th. Kauffmann, U. Koch, F. Steinseifer, A. Vahrenhorst, Tetrahedron Lett. 1977, 3341.

Abstract

A modified alternative to the Wittig reaction utilizes (triphenylstannyl)methyllithium. Yields are good; the alcohol does not have to be isolated.

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