Bis(η6-naphthalene)chromium(0)

Authors


  • Metal π-Complexes of Benzene Derivatives, Part 8. This work was supported by the Deutsche Forschungsgemeinschaft and the Fonds der Chemischen Industrie. Part 7: Ch. Elschenbroich, J. Heck, Angew. Chem. 85, 497 (1977); Angew. Chem. Int. Ed. Engl. 16, 479 (1977).

Abstract

original image

More than 20 years after bis(η-benzene)chromium(0) the higher homolog, naphthalene derivative (1), has now been prepared. It was synthesized by cocondensation of metal atom and ligand at −196°C. Neutral naphthalene complexes of this kind were formerly unknown.

Ancillary